Did you figure this out yet?
Other than using it for tracing/double checking circuits I'd forget about how the 2.2 engine harness is wired and focus on the 4.8. Definitely leave circuit 420 hooked up to PCM - C1 (33) and tie it to the S10 C101 (E)
Some of the C101 confusion comes from the fact that somewhere between 98 and 2000 they switched from the 10 pin to the 16 pin on the 2.2 and eventually on the 4.3 as well halfway through 2002. The factory schematics and end views do have a few errors that I've run into before.
C100 (N) provides Ignition power to the 4WD system. Both the Blazer and the full size truck use circuit 241 off each of their 4WD fuses. If you don't have 4WD don't worry about it.
UBEC - C2 (A3) feeds PCM - C2 pin 11 the AC High Pressure Re-Circulation Switch Signal with the full size truck A/C wiring. On the FST that switch appears to be wired into either the chassis or forward lamp harness and passes back to the PCM through the fuse block.
If you haven't found these resources already I use them in a pinch when the files I saved from the factory service manuals aren't complete
http://www.lt1swap.com/2000harness.htmWiring Diagrams and Repair Info - 1999 Silverado should be pretty close to your 2002. 2003 they started using drive by wire for the throttle.